Not sure why you want the longest barrel.
If it is for more velocity, here is some data worth looking at:
http://www.ballisticsbytheinch.com/357mag.htmlPast 14 inches long not much happened velocity wise. In fact, in a few of the loads the velocity appeared to drop off past 14 inches.
There is data for lots of pistol cartridges on that same web site. For the most part, after 14 inches thee was little or no gain. In some calibers, things went down hill after 5-6 inches.
I guess it sort of makes sense. Pistol cartridges were originally designed to be fired in pistols. The case capacity and the classic powders were all designed for shorter barrels.
That's not to say that with handloading some improvement geared specifically at longer barrels can not be made over factory ammo. Looking at load data specific to the 14" barrel T/C contender or specific to rifles would help. Heavy bullets (180 gr), slow powder (H110) would use a bit more barrel.