This all kinda depends on your intent.
The first place to start is to create dummy rounds (no primer no powder) just like the current pistol rounds, 10 will be enough.
Test the dummy rounds in the rifle, if they load and eject fine your intent comes in to play.
If you are just shooting sass and velocity and terminal effects do not matter, shoot the same loads as in your pistol.
If the dummy rounds have feed issues try seating the bullets out farther to achieve what works for your rifle. As stated in other posts 1.50 inches usually works, your rifle might work shorter.
Bullet shape does matter Flat point round nose or Truncated cone generally will feed much better than semi wad cutters. You may find the rifle likes a moderate to heavy roll crimp to aid in chambering. If your rounds are too short the rossi may just throw them out the top when the elevator pops up.
If you are looking for kinda max velocity you can use +P data for the rifle, but those rounds can never be shot in your pistol. Seriously if you are looking to max out velocity, I would recommend loading .357 mag cases for the rifle. That way a hot load will not chamber in your rather weak but cool revolvers. I have had good luck with HS 6, HP38, AA2, Red Dot, Nitro 100 old and new in 38.
If you troll the internet there is a guy out there that makes a special tool head with a spacer that allows for a more or less instant conversion from .38 to .357 mag for dillions.